Source:http://linkedlifedata.com/resource/pubmed/id/19371063
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
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| pubmed:dateCreated |
2009-5-26
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| pubmed:abstractText |
The magnetic behavior of N,N'-ethylenebis(salicylideniminato)cobalt(II) (Co(II)Salen, 1) has been reinvestigated and reveals spin-crossover behavior above 295 K. It has a singlet ground state and a triplet excited state at 30 K (21 cm(-1); 60 cal/mol) above the ground state, and at a higher temperature spin crossover to the quartet, a second excited state occurs.
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| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:citationSubset |
IM
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| pubmed:chemical | |
| pubmed:status |
MEDLINE
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| pubmed:month |
Jun
|
| pubmed:issn |
1520-510X
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| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
1
|
| pubmed:volume |
48
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
4593-4
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| pubmed:meshHeading |
pubmed-meshheading:19371063-Cobalt,
pubmed-meshheading:19371063-Dimerization,
pubmed-meshheading:19371063-Ethylenediamines,
pubmed-meshheading:19371063-Magnetics,
pubmed-meshheading:19371063-Models, Molecular,
pubmed-meshheading:19371063-Molecular Structure,
pubmed-meshheading:19371063-Organometallic Compounds,
pubmed-meshheading:19371063-Quantum Theory,
pubmed-meshheading:19371063-Temperature
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| pubmed:year |
2009
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| pubmed:articleTitle |
Tristability arising from singlet-triplet and quartet spin states for dimeric Co(II)salen.
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| pubmed:affiliation |
Department of Chemistry, 315 South 1400 East, Room 2124, University of Utah, Salt Lake City, Utah 84112-0850, USA.
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| pubmed:publicationType |
Journal Article
|