Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
16
pubmed:dateCreated
2009-4-22
pubmed:abstractText
We produced millions of morphologically identical platinum catalyst nanoparticles in the form of ordered arrays epitaxially grown on (111), (100), and (110) strontium titanate substrates using electron beam lithography. The ability to design, produce, and characterize the catalyst nanoparticles allowed us to relate microscopic morphologies with macroscopic catalytic reactivities. We evaluated the activity of three different arrays containing different ratios of (111) and (100) facets for an oxygen-reduction reaction, the most important reaction for fuel cells. Increased catalytic activity of the arrays points to a possible cooperative interplay between facets with different affinities to oxygen. We suggest that the surface area of (100) facets is one of the key factors governing catalyst performance in the electrochemical reduction of oxygen molecules.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
29
pubmed:volume
131
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
5732-3
pubmed:year
2009
pubmed:articleTitle
Shape-dependent activity of platinum array catalyst.
pubmed:affiliation
Safarik University, Faculty of Sciences and, Institute of Experimental Physics, SAS, Kosice 04154, Slovakia. vladimir.komanicky@upjs.sk
pubmed:publicationType
Journal Article