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pubmed-article:19296636pubmed:abstractTextFeCl(2) catalyzes the oxidative C-C cross-coupling of tertiary amines with terminal alkynes into propargylamines using (t-BuO)(2) as oxidant. The reaction can be applied to aromatic and aliphatic amines and alkynes without solvent. High chemoselectivity for aminomethyl groups is due to a steric factor.lld:pubmed
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pubmed-article:19296636pubmed:articleTitleChemoselective C-H bond activation: ligand and solvent free iron-catalyzed oxidative C-C cross-coupling of tertiary amines with terminal alkynes. Reaction scope and mechanism.lld:pubmed
pubmed-article:19296636pubmed:affiliationLaboratoire de glycochimie et de synthese asymetrique (LGSA), Swiss Federal Institute of Technology of Lausanne (EPFL), CH 1015 Lausanne, Switzerland.lld:pubmed
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