Source:http://linkedlifedata.com/resource/pubmed/id/19281251
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
8
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pubmed:dateCreated |
2009-4-9
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pubmed:abstractText |
A cationic palladium(II)/(S)-xyl-Segphos complex catalyzes enantioselective cycloisomerizations of N-alkenyl arylethynylamides leading to axially chiral 4-aryl-2-pyridones in high yields with high ee values. The present catalysis represents the first enantioselective construction of axial chirality by the transition-metal-catalyzed cycloisomerization.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1523-7052
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
16
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pubmed:volume |
11
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1805-8
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pubmed:meshHeading |
pubmed-meshheading:19281251-Alkenes,
pubmed-meshheading:19281251-Alkynes,
pubmed-meshheading:19281251-Catalysis,
pubmed-meshheading:19281251-Combinatorial Chemistry Techniques,
pubmed-meshheading:19281251-Cyclization,
pubmed-meshheading:19281251-Molecular Structure,
pubmed-meshheading:19281251-Palladium,
pubmed-meshheading:19281251-Pyridones,
pubmed-meshheading:19281251-Stereoisomerism
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pubmed:year |
2009
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pubmed:articleTitle |
Highly enantioselective construction of axial chirality by palladium-catalyzed cycloisomerization of N-alkenyl arylethynylamides.
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pubmed:affiliation |
Department of Applied Chemistry, Graduate School of Engineering, and Instrumentation Analysis Center, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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