Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2009-2-27
pubmed:abstractText
Hydrogen can be important clean fuel for future. Among different technologies for hydrogen production, oxygenic natural and artificial photosyntheses using direct photochemistry in synthetic complexes have a great potential to produce hydrogen, since both use clean and cheap sources: water and solar energy. Artificial photosynthesis is one way to produce hydrogen from water using sunlight by employing biomimetic complexes. However, splitting of water into protons and oxygen is energetically demanding and chemically difficult. In oxygenic photosynthetic microorganisms such as algae and cyanobacteria, water is split into electrons and protons, which during primary photosynthetic process are redirected by photosynthetic electron transport chain, and ferredoxin, to the hydrogen-producing enzymes hydrogenase or nitrogenase. By these enzymes, e- and H+ recombine and form gaseous hydrogen. Biohydrogen activity of hydrogenase can be very high but it is extremely sensitive to photosynthetic O2. In contrast, nitrogenase is insensitive to O2, but has lower activity. At the moment, the efficiency of biohydrogen production is low. However, theoretical expectations suggest that the rates of photon conversion efficiency for H2 bioproduction can be high enough (>10%). Our review examines the main pathways of H2 photoproduction by using of photosynthetic organisms and biomimetic photosynthetic systems.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1474-905X
pubmed:author
pubmed:issnType
Print
pubmed:volume
8
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
148-56
pubmed:dateRevised
2010-11-18
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Hydrogen photoproduction by use of photosynthetic organisms and biomimetic systems.
pubmed:affiliation
Institute of Basic Biological Problems, Russian Academy of Sciences, Pushchino, Moscow Region 142290, Russia. Suleyman@ibbp.psn.ru
pubmed:publicationType
Journal Article, Review, Research Support, Non-U.S. Gov't