Source:http://linkedlifedata.com/resource/pubmed/id/19245209
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
12
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pubmed:dateCreated |
2009-3-24
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pubmed:abstractText |
The short-lived (<1 ps) initial intermediate state P(+)B(L)(-) in the photoinduced charge separation process of the bacterial photosynthetic reaction center has been trapped in two D(LL)-based Rhodobacter capsulatus mutants that have Tyr at position M208 and lack the bacteriopheophytin electron acceptor H(L). Transient state P(+)B(L)(-) is characterized by a 1017 nm bacteriochlorophyll anion absorption band and decays by charge recombination with a lifetime of several hundred picoseconds at 295 K. P(+)B(L)(-) is not observed in an otherwise identical mutant that has Phe at M208, which appears to make the state thermodynamically inaccessible from the excited primary electron donor P*.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Mar
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pubmed:issn |
1520-4995
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
31
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pubmed:volume |
48
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2571-3
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pubmed:meshHeading |
pubmed-meshheading:19245209-Kinetics,
pubmed-meshheading:19245209-Models, Molecular,
pubmed-meshheading:19245209-Pheophytins,
pubmed-meshheading:19245209-Photosynthetic Reaction Center Complex Proteins,
pubmed-meshheading:19245209-Protein Conformation,
pubmed-meshheading:19245209-Rhodobacter capsulatus
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pubmed:year |
2009
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pubmed:articleTitle |
Trapping the P+B(L)- initial intermediate state of charge separation in photosynthetic reaction centers from Rhodobacter capsulatus.
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pubmed:affiliation |
Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.
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