19243097

Source:http://linkedlifedata.com/resource/pubmed/id/19243097

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007018, umls-concept:C0439855, umls-concept:C1948027
pubmed:issue	10
pubmed:dateCreated	2009-3-11
pubmed:abstractText	A ditantalum hydride complex undergoes head-to-head C-C coupling of six CO molecules under mild conditions to produce an octaanionic C(6)O(6) unit. During the reaction, eight-electron reduction of six CO molecules takes place. In the product, the C(6)O(6) unit is coordinated to four tantalum metals through six oxygen and two carbon atoms. The geometrical parameters within the Ta(4)C(6)O(6) core indicate significant contribution from a hexatriene-hexaolate form.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Mar
pubmed:issn	1520-5126
pubmed:author	pubmed-author:IshidaYutakaY, pubmed-author:KawaguchiHiroyukiH, pubmed-author:MatsuoTsukasaT, pubmed-author:WatanabeTakahitoT
pubmed:issnType	Electronic
pubmed:day	18
pubmed:volume	131
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3474-5
pubmed:year	2009
pubmed:articleTitle	Reductive coupling of six carbon monoxides by a ditantalum hydride complex.
pubmed:affiliation	Department of Chemistry, Tokyo Institute of Technology, Ookayama, Meguro-ku, Tokyo 152-8551, Japan.
pubmed:publicationType	Journal Article