Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1-3
pubmed:dateCreated
2009-5-26
pubmed:abstractText
Adsorption of hexavalent chromium [Cr(VI)] onto a loamy sand soil was studied using batch and steady flow tests with contaminant solutions at pH 2, 5 and 7. In all the cases the adsorption of Cr(VI) decreased with increasing pH. The hexavalent chromium speciation and its presence as different oxyanions, according to the solution pH, were the main variables affecting the adsorption process. The influence of the ratio soil/solution concentration was also studied in flow systems at pH 2. Chromium retention increased with the increasing of its concentration in the influent solution. A two-site adsorption model was fitted to the breakthrough curves of hexavalent chromium solutions in order to estimate the Freundlich (k(F)) and Langmuir (S(max)) adsorption parameters, using CXTFIT code. These values were compared to those determined by batch tests and it was concluded that batch tests tended to underestimate these parameters. Nevertheless, they followed the same trend as the parameters determined in opened system, even when the pH of the initial solution was modified.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Aug
pubmed:issn
1873-3336
pubmed:author
pubmed:issnType
Electronic
pubmed:day
15
pubmed:volume
167
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
756-62
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Modelling of the Cr(VI) transport in typical soils of the North of Portugal.
pubmed:affiliation
IBB-Institute for Biotechnology and Bioengineering, Centre of Biological Engineering, University of Minho, Braga, Portugal. bfonseca@deb.uminho.pt
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't