Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2009-2-11
pubmed:abstractText
We produced large binder-free multi-walled carbon nanotube (MWNT) blocks from fluorinated MWNTs using thermal heating and a compressing method in vacuo. This technique resulted in the formation of covalent MWNT networks generated by the introduction of sp(3)-hybridized carbon atoms that cross-link between nanotubes upon de-fluorination. The resulting carbon nanotube blocks are lighter than graphite, can be machined and polished, and possess average bending strengths of 102.2 MPa, a bending modulus of 15.4 GPa, and an electrical conductivity of 2.1 x 10(2) S/cm. Although each nanotube exhibits a random structure in these blocks, the mechanical properties are 3 times higher than those obtained for commercial graphite. On the basis of theoretical molecular dynamics simulations, a model is presented for the nanotube interconnecting mechanism upon de-fluorination.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1936-086X
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
2
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
348-56
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Super-robust, lightweight, conducting carbon nanotube blocks cross-linked by de-fluorination.
pubmed:affiliation
Graduate School of Environmental Studies, Tohoku University, Aoba 6-6-20, Aramaki, Aoba-ku, Sendai 980-8579, Japan. hige@bucky1.kankyo.tohoku.ac.jp
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't