Source:http://linkedlifedata.com/resource/pubmed/id/19206637
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
2
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pubmed:dateCreated |
2009-2-11
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pubmed:abstractText |
We produced large binder-free multi-walled carbon nanotube (MWNT) blocks from fluorinated MWNTs using thermal heating and a compressing method in vacuo. This technique resulted in the formation of covalent MWNT networks generated by the introduction of sp(3)-hybridized carbon atoms that cross-link between nanotubes upon de-fluorination. The resulting carbon nanotube blocks are lighter than graphite, can be machined and polished, and possess average bending strengths of 102.2 MPa, a bending modulus of 15.4 GPa, and an electrical conductivity of 2.1 x 10(2) S/cm. Although each nanotube exhibits a random structure in these blocks, the mechanical properties are 3 times higher than those obtained for commercial graphite. On the basis of theoretical molecular dynamics simulations, a model is presented for the nanotube interconnecting mechanism upon de-fluorination.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
1936-086X
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pubmed:author |
pubmed-author:HashidaToshiyukiT,
pubmed-author:HashiguchiShinjiS,
pubmed-author:JeyadevanBalachandranB,
pubmed-author:KimuraHisamichiH,
pubmed-author:MotomiyaKenichiK,
pubmed-author:OkuboAkiraA,
pubmed-author:OotsuboMakotoM,
pubmed-author:SatoYoshinoriY,
pubmed-author:TerronesMauricioM,
pubmed-author:TohjiKazuyukiK,
pubmed-author:Van LierGregoryG,
pubmed-author:YamamotoGoG
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pubmed:issnType |
Electronic
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pubmed:volume |
2
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
348-56
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pubmed:meshHeading |
pubmed-meshheading:19206637-Cross-Linking Reagents,
pubmed-meshheading:19206637-Crystallization,
pubmed-meshheading:19206637-Electric Conductivity,
pubmed-meshheading:19206637-Electrochemistry,
pubmed-meshheading:19206637-Fluorine,
pubmed-meshheading:19206637-Macromolecular Substances,
pubmed-meshheading:19206637-Materials Testing,
pubmed-meshheading:19206637-Molecular Conformation,
pubmed-meshheading:19206637-Nanostructures,
pubmed-meshheading:19206637-Nanotechnology,
pubmed-meshheading:19206637-Particle Size,
pubmed-meshheading:19206637-Surface Properties
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pubmed:year |
2008
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pubmed:articleTitle |
Super-robust, lightweight, conducting carbon nanotube blocks cross-linked by de-fluorination.
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pubmed:affiliation |
Graduate School of Environmental Studies, Tohoku University, Aoba 6-6-20, Aramaki, Aoba-ku, Sendai 980-8579, Japan. hige@bucky1.kankyo.tohoku.ac.jp
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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