Source:http://linkedlifedata.com/resource/pubmed/id/19190366
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 2
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| pubmed:dateCreated |
2009-2-4
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| pubmed:abstractText |
Two conformational polymorphs of trans-chlorido(phenyl)bis(triphenylphosphine)nickel(II), [Ni(C(6)H(5))Cl(C(18)H(15)P)(2)], (1), viz. orange needle-shaped crystals (form I) and brown prism-shaped crystals (form II), were obtained under different crystallization conditions from a mixture of toluene and n-hexane, and characterized by single-crystal X-ray diffraction at low temperature. These two forms were compared with that published previously [Zeller, Herdtweck & Strassner (2003). Eur. J. Inorg. Chem. pp. 1802-1806], characterized at room temperature. Additionally, blue-green prisms of a 1:1 cocrystal of complex (1) with chloridobis(triphenylphosphine)nickel(I), (2), viz. trans-chlorido(phenyl)bis(triphenylphosphine)nickel(II)-chloridobis(triphenylphosphine)nickel(I) (1/1), [Ni(C(6)H(5))Cl(C(18)H(15)P)(2)].[NiCl(C(18)H(15)P)(2)], (3), were obtained concomitantly with form I. In forms I and II, as well as in the cocrystal, the overall crystal packings are determined by an energetic interplay between intramolecular torsions and weak intermolecular C-H...pi and C-H...Cl interactions.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Feb
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| pubmed:issn |
1600-5759
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
65
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m110-4
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| pubmed:year |
2009
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| pubmed:articleTitle |
trans-Chlorido(phenyl)bis(triphenylphosphine)nickel(II) and its 1:1 cocrystal with chloridobis(triphenylphosphine)nickel(I).
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| pubmed:affiliation |
Centro de Química Estrutural, Departamento de Engenharia Química e Biológica, Instituto Superior Técnico, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal.
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| pubmed:publicationType |
Journal Article
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