Source:http://linkedlifedata.com/resource/pubmed/id/19189360
Switch to
| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
|
| pubmed:dateCreated |
2009-3-2
|
| pubmed:abstractText |
On a plane: Addition of PhCCH to Ar'GaGaAr' (Ar' = 2,6-(2,6-iPr(2)C(6)H(3))(2)C(6)H(3)) yielded the 1,4-digallacyclohexadiene [{Ar'GaC(Ph)CH}(2)] (1), which afforded the 1,4-digallatabenzene dianion [Ar'GaC(Ph)CH](2)(2-) (2) upon reduction with potassium (see scheme; C gray, Ga green, K blue). Structural parameters, DFT calculations, and (1)H NMR spectroscopy support aromatic character of 2.
|
| pubmed:language |
eng
|
| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:issn |
1521-3773
|
| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:volume |
48
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
2027-30
|
| pubmed:year |
2009
|
| pubmed:articleTitle |
Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2OEt2: from digallene to digallacyclohexadiene to digallatabenzene.
|
| pubmed:affiliation |
Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA.
|
| pubmed:publicationType |
Journal Article
|