Source:http://linkedlifedata.com/resource/pubmed/id/19170150
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
9
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pubmed:dateCreated |
2009-2-19
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pubmed:abstractText |
No legendary Prussian order! The distribution of vacancies in Prussian blue analogues is not random, and the spin density on the Cd(2+) ion varies depending on the number of paramagnetic ions in its surroundings. This conclusion follows from (113)Cd solid-state magic-angle spinning NMR studies of [Cd(3){Fe/Co(CN)(6)}(2)] x 15 H(2)O, where the presence of small but significant spin density on the observed (113)Cd nucleus leads to improved spectral resolution.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:issn |
1521-3773
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:volume |
48
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1673-6
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pubmed:dateRevised |
2009-4-28
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pubmed:year |
2009
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pubmed:articleTitle |
Revisiting prussian blue analogues with solid-state MAS NMR spectroscopy: spin density and local structure in [Cd3{Fe(CN)6}2] x 15 H2O.
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pubmed:affiliation |
Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris6, UMR 7071, Paris 75252, France.
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pubmed:publicationType |
Journal Article
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