Linked Life Data

19133743

Source:http://linkedlifedata.com/resource/pubmed/id/19133743

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2009-2-4
pubmed:abstractText
Ligand-free Pd(OAc)2 was found to catalyze very efficiently the direct arylation of thiazole derivatives under very low catalyst concentration. By using activated aryl bromides, the reaction can be performed employing as little as 0.1-0.001 mol % catalyst. With such substrates, this procedure is economically and environmentally attractive. On the other hand, in the presence of more challenging substrates, such as some strongly deactivated or highly congested aryl bromides, in some cases, disappointing results were obtained.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Feb
pubmed:issn
1520-6904
pubmed:author
pubmed:issnType
Electronic
pubmed:day
6
pubmed:volume
74
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1179-86
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
Ligand-free palladium-catalyzed direct arylation of thiazoles at low catalyst loadings.
pubmed:affiliation
Institut Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes Catalyse et Organometalliques, Campus de Beaulieu, 35042 Rennes, France.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't