Source:http://linkedlifedata.com/resource/pubmed/id/19129592
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 1
|
| pubmed:dateCreated |
2009-1-8
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| pubmed:abstractText |
The crystal structure of the title compound, [Pt(C(8)H(18)P(2))(C(9)H(21)P)(C(18)H(15)P)] or [(Ph(3)P)((t)Bu(2)PMe)Pt(eta(2)-(t)Bu(2)PP)], contains four molecules in the asymmetric unit with slightly different conformations. The P-P distances in the (t)Bu(2)PP ligands are similar for all four molecules [2.0661 (13)-2.0678 (13) A] and indicate a multiple character of the P-P bond in the (t)Bu(2)PP ligand. Molecules of the asymmetric unit can be assembled into a tetrahedron that fulfils the requirements for a rhombic disphenoid. The coordination of the Pt atom in all four molecules is square planar, with r.m.s. deviations from the PtP(4) planes in the range 0.03-0.05 A. All planes of the PtP(4) groups are approximately parallel to the ab plane of the unit cell. The structure represents an unusual unsymmetrical platinum phosphinidene derivative.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jan
|
| pubmed:issn |
1600-5759
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| pubmed:author | |
| pubmed:issnType |
Electronic
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| pubmed:volume |
65
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
m21-3
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| pubmed:year |
2009
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| pubmed:articleTitle |
(Di-tert-butylmethylphosphane)(eta2-di-tert-butylphosphanylphosphinidene)(triphenylphosphane)platinum(0).
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| pubmed:affiliation |
Department of Inorganic Chemistry, Gda?sk University of Technology, 11/12 G. Narutowicz Street, 80952 PL Gda?sk, Poland.
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| pubmed:publicationType |
Journal Article
|