Linked Life Data

19101941

Source:http://linkedlifedata.com/resource/pubmed/id/19101941

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2009-1-27
pubmed:abstractText
A Pd on porous glass catalyst system was used in the liquid-phase hydrogenation of terpenoid substrates with dihydrogen at room temperature and atmospheric pressure. A multitude of substances were hydrogenated selectively with yields of 90-100 %. In all experiments, only C--C, C--N, and N--N double bonds were hydrogenated. Studies revealed that carbonyl and aromatic double bonds are inert towards catalytic reduction with dihydrogen under the conditions employed. In some cases, hydrogenation was accompanied by isomerization, so that treatment of beta-pinene, for example, afforded isomeric alpha-pinene, which was subsequently hydrogenated to pinane.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:issn
1864-564X
pubmed:author
pubmed:issnType
Electronic
pubmed:volume
2
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
77-82
pubmed:meshHeading
pubmed:year
2009
pubmed:articleTitle
A practical approach for ambient-pressure hydrogenations using Pd on porous glass.
pubmed:affiliation
Institute for Technical Chemistry and Environmental Chemistry, Friedrich-Schiller University Jena, Jena, Germany.
pubmed:publicationType
Journal Article