Source:http://linkedlifedata.com/resource/pubmed/id/19089008
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
2
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| pubmed:dateCreated |
2008-12-17
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| pubmed:abstractText |
Reversible photomagnetic effects were demonstrated at room temperature by the use of a new iron(II) complex t100c0-[Fe()3](BF4)(2).3H2O ( =phenyl(2-pyridin-2-yl-3H-benzoimidazol-5-yl)diazene), based on the strategy of the so-called "ligand-driven light-induced spin change" (LD-LISC) effect. The complex showed thermal spin crossover in both solid and solution states, showing a transition temperature T1/2=279(16) K in acetone. trans-cis Photoisomerization of azobenzene moieties using different energy lights afforded reversible photomagnetic effects, which were directly determined using the Evans 1H NMR method.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jan
|
| pubmed:issn |
1477-9226
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
14
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
280-4
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| pubmed:year |
2009
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| pubmed:articleTitle |
Reversible light-induced magnetization change in an azobenzene-attached pyridylbenzimidazole complex of iron(II) at room temperature.
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| pubmed:affiliation |
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyoku, Tokyo 113-0033, Japan.
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| pubmed:publicationType |
Journal Article
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