Linked Life Data

19072016

Source:http://linkedlifedata.com/resource/pubmed/id/19072016

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2008-12-31
pubmed:abstractText
Syndiotactic poly(N-n-propylacrylamide)s (PNNPAM) with various racemo (r) diad contents were synthesized, and their phase transition behaviors were studied by high-sensitivity differential scanning calorimetry and FT-IR spectroscopy. The cooperativity of the phase transition increased with the increase in the r diad content. Compared with the atactic PNNPAM, the number of cooperative units, which shows the monomeric units length undergoing cooperative phase transition, increased 2.5- to 4-fold in the syndiotactic polymers. From the results of FT-IR spectroscopy and quantum chemical calculations, it was determined that the high cooperativity of the syndiotactic polymers resulted from local formation of an ordered structure in a dehydrated state.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jan
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
6
pubmed:volume
25
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
48-50
pubmed:year
2009
pubmed:articleTitle
Syndiotactic poly(N-n-propylacrylamide) shows highly cooperative phase transition.
pubmed:affiliation
Department of Applied Chemistry, Center for Future Chemistry, and Institute for Material Chemistry and Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan. moritcm@mbox.nc.kyushu-u.ac.jp
pubmed:publicationType
Journal Article