Linked Life Data

19053424

Source:http://linkedlifedata.com/resource/pubmed/id/19053424

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
51
pubmed:dateCreated
2008-12-18
pubmed:abstractText
A series of di-gadolinium endohedrals that extends from Gd(2)C(90) to Gd(2)C(124) has been detected by mass spectrometry of the o-dichlorobenzene extract of the carbon soot produced by direct current arcing of graphite rods filled with a mixture of Gd(2)O(3) and graphite powder. Chromatographic separation has led to the isolation of pure samples of two isomers of Gd(2)C(94) and the complete series from Gd(2)C(96) to Gd(2)C(106). Endohedral fullerenes of the type M(2)C(2n) can exist as the conventional endohedral, M(2)@C(2n), or as the carbide-containing endohedral, M(2)C(2)@C(2n-2). Crystallographic characterization of the more rapidly eluting isomer of Gd(2)C(94) reveals that it possesses the carbide structure, Gd(2)C(2)@D(3)(85)-C(92). Computational studies suggest that the more slowly eluting isomer of Gd(2)C(94) may be a conventional endohedral, Gd(2)@C(2)(121)-C(94).
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Dec
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
24
pubmed:volume
130
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
17296-300
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Detection of a family of gadolinium-containing endohedral fullerenes and the isolation and crystallographic characterization of one member as a metal-carbide encapsulated inside a large fullerene cage.
pubmed:affiliation
Zhejiang-California International NanoSystems Institute, Department of Chemistry, Zhejiang University, Hangzhou 310027, China.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S.