Source:http://linkedlifedata.com/resource/pubmed/id/19030581
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
45
|
| pubmed:dateCreated |
2008-11-25
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| pubmed:abstractText |
Reaction of 3,5-Pr(i)2Ar*Fe(eta6-C6H6)(3,5-Pr(i)2Ar* = C6H1-2,6-(C6H2)-2,4,6-Pr(i)3)(2)-3,5-Pr(i)2) with (N3C6H3)-2,6-Mes2 (Mes = (C6H2)-2,4,6-Me3) afforded the dimeric iron(II) amido/aryl complex {CH2C6H(2)-2(C6H3)-2-N(H)FeAr*-3,5-Pr(i)2)-3,5-Me2}2 (1) which arises via methyl hydrogen abstraction by nitrogen and dimerization of the radical via C-C bond formation; in contrast, reaction of 3,5-Pr(i)2Ar*Fe(eta6)-C6H6) with N3(1-Ad) (1-Ad = 1-adamantanyl) gave the iron(V) bis(imido) complex 3,5-Pr(i)2Ar*Fe{N(1-Ad)}2 (2).
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Dec
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| pubmed:issn |
1359-7345
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
7
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
6045-7
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| pubmed:year |
2008
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| pubmed:articleTitle |
Reaction of a sterically encumbered iron(I) aryl/arene with organoazides: formation of an iron(V) bis(imide).
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| pubmed:affiliation |
Department of Chemistry, University of California, One Shields Avenue, Davis, CA 95616, USA.
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| pubmed:publicationType |
Journal Article
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