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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2009-2-20
pubmed:abstractText
The synthesis and X-ray crystal structures of five N-heterocyclic stannylenes are reported. These compounds, containing a variety of backbones, were prepared by the salt metathesis of the appropriate dilithiated diamide with SnCl(2) and show a high degree of thermal stability compared to the corresponding species with unsaturated backbones. If bulky diisopropylphenyl groups are attached to the nitrogen centers then the structures are monomeric, but when the less bulky mesityl groups are employed the solid-state structure was shown to be dimeric.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Dec
pubmed:issn
1520-510X
pubmed:author
pubmed:issnType
Electronic
pubmed:day
1
pubmed:volume
47
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
11367-75
pubmed:year
2008
pubmed:articleTitle
Synthesis and structural characterization of tin analogues of N-heterocyclic carbenes.
pubmed:affiliation
School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.
pubmed:publicationType
Journal Article