Source:http://linkedlifedata.com/resource/pubmed/id/18972460
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
2
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pubmed:dateCreated |
2008-12-29
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pubmed:abstractText |
Complex electron transfer reactions have been characterized whereby in addition to electron transfer, subsequent electrochemical, chemical and even in some cases biological consequences occur. These include a secondary electron transfer that leads to a major rearrangement of the electronic structure, such that an initial oxidation leads to a reduction (or an initial reduction leads to an oxidation) for these valence ambiguous compounds. Mixed valency and valence-tautomeric behaviors can additionally result from these complex electron-transfer-induced reactions.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:issn |
1521-3773
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:volume |
48
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
262-72
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pubmed:meshHeading | |
pubmed:year |
2009
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pubmed:articleTitle |
Oxidation leading to reduction: redox-induced electron transfer (RIET).
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pubmed:affiliation |
Department of Chemistry, University of Utah, Salt Lake City, UT 84112-0850, USA. jsmiller@chem.utah.edu
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pubmed:publicationType |
Journal Article,
Review
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