18937416

Source:http://linkedlifedata.com/resource/pubmed/id/18937416

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0029144, umls-concept:C0205344, umls-concept:C0449830, umls-concept:C0871161, umls-concept:C2699488, umls-concept:C2827597
pubmed:issue	22
pubmed:dateCreated	2008-11-14
pubmed:abstractText	A racemic mixture of three-layered [3.3]paracyclophane ([3.3]PCP), 1, has been resolved into two enantiomers, and their absolute configuration was determined from a comparison of experimental chiroptical properties and density functional theory (DFT) calculations. A simple model comprising two p-xylenes and 1,2,4,5-tetramethylbenzene (durene) was used to explain the origin of the chiroptical properties of the three-layered cyclophane system.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Nov
pubmed:issn	1520-6904
pubmed:author	pubmed-author:KobayashiNagaoN, pubmed-author:MatsumotoTaisukeT, pubmed-author:MuranakaAtsuyaA, pubmed-author:ShibaharaMasahikoM, pubmed-author:ShinmyozuTeruoT, pubmed-author:WatanabeMotonoriM
pubmed:issnType	Electronic
pubmed:day	21
pubmed:volume	73
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	9125-8
pubmed:year	2008
pubmed:articleTitle	Optical resolution, absolute configuration, and chiroptical properties of three-layered [3.3]paracyclophane.
pubmed:affiliation	Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, 980-8578, Japan.
pubmed:publicationType	Journal Article