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Predicate | Object |
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rdf:type | |
lifeskim:mentions |
umls-concept:C0005767,
umls-concept:C0006632,
umls-concept:C0011744,
umls-concept:C0023175,
umls-concept:C0037806,
umls-concept:C0042037,
umls-concept:C0221102,
umls-concept:C0242485,
umls-concept:C0331858,
umls-concept:C1704640,
umls-concept:C1706515,
umls-concept:C1706907,
umls-concept:C1883073,
umls-concept:C1947976,
umls-concept:C2346501
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pubmed:issue |
9
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pubmed:dateCreated |
1991-10-24
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pubmed:abstractText |
Direct measurement of lead and cadmium in blood and urine by electrothermal atomic absorption spectrometry with deuterium background correction (D2-AAS) is prone to severe matrix and spectral interferences. We overcame these effects by coating the L'vov platform with ammonium molybdate, reducing the atomization time, introducing a post-atomization cooling step, carefully selecting ashing and atomization temperatures, and using an appropriate procedure for matrix modification. To determine Pb and Cd in blood and urine, we used matrix-matched calibration curves. With the proposed procedure for sample preparation, both Pb and Cd in whole blood can be determined in the same diluted sample. Results obtained by D2-AAS correlate closely with those by Zeeman-corrected AAS. Detection limits (mean blank + 3 SDblank) for Pb in urine and blood were 4 micrograms/L. For cadmium, the detection limits were 0.4 and 0.1 micrograms/L for urine and blood analysis, respectively. Between-run CVs were less than 5.0%.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
0009-9147
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
37
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1583-8
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pubmed:dateRevised |
2004-11-17
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pubmed:meshHeading | |
pubmed:year |
1991
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pubmed:articleTitle |
Elimination of matrix and spectral interferences in the measurement of lead and cadmium in urine and blood by electrothermal atomic absorption spectrometry with deuterium background correction.
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pubmed:affiliation |
University of Antwerp, Department of Nephrology-Hypertension, Belgium.
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pubmed:publicationType |
Journal Article
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