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18839940
Source:
http://linkedlifedata.com/resource/pubmed/id/18839940
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rdf:type
pubmed:Citation
lifeskim:mentions
umls-concept:C0020286
,
umls-concept:C0020930
,
umls-concept:C0332514
pubmed:issue
44
pubmed:dateCreated
2008-10-29
pubmed:abstractText
When combined with a chiral phosphate counteranion, a chiral diamine-ligated Ir(III) catalyst displayed excellent enantioselectivities in the asymmetric hydrogenation of a wide range of acyclic imines, affording chiral amines in up to 99% ee.
pubmed:language
eng
pubmed:journal
http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:citationSubset
IM
pubmed:chemical
http://linkedlifedata.com/resource/pubmed/chemical/Amines
,
http://linkedlifedata.com/resource/pubmed/chemical/Diamines
,
http://linkedlifedata.com/resource/pubmed/chemical/Imines
,
http://linkedlifedata.com/resource/pubmed/chemical/Iridium
,
http://linkedlifedata.com/resource/pubmed/chemical/Organometallic Compounds
,
http://linkedlifedata.com/resource/pubmed/chemical/Phosphoric Acid Esters
pubmed:status
MEDLINE
pubmed:month
Nov
pubmed:issn
1520-5126
pubmed:author
pubmed-author:LiChaoqunC
,
pubmed-author:Villa-MarcosBarbaraB
,
pubmed-author:WangChaoC
,
pubmed-author:XiaoJianliangJ
pubmed:issnType
Electronic
pubmed:day
5
pubmed:volume
130
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
14450-1
pubmed:dateRevised
2009-1-27
pubmed:meshHeading
pubmed-meshheading:18839940-Amines
,
pubmed-meshheading:18839940-Catalysis
,
pubmed-meshheading:18839940-Diamines
,
pubmed-meshheading:18839940-Hydrogenation
,
pubmed-meshheading:18839940-Imines
,
pubmed-meshheading:18839940-Iridium
,
pubmed-meshheading:18839940-Organometallic Compounds
,
pubmed-meshheading:18839940-Phosphoric Acid Esters
,
pubmed-meshheading:18839940-Stereoisomerism
pubmed:year
2008
pubmed:articleTitle
Chiral counteranion-aided asymmetric hydrogenation of acyclic imines.
pubmed:affiliation
Department of Chemistry, Liverpool Centre for Materials and Catalysis, University of Liverpool, Liverpool L69 7ZD, UK.
pubmed:publicationType
Journal Article
,
Research Support, Non-U.S. Gov't