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rdf:type |
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|
lifeskim:mentions |
|
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pubmed:issue |
38
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|
pubmed:dateCreated |
2008-9-25
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pubmed:abstractText |
The enantioselective BINOL-phosphate catalyzed formation of a quaternary carbon center, bearing a N-atom has been achieved through the self-coupling reaction of enamides; the corresponding products have been isolated in up to >99% ee and their application for the synthesis of versatile synthetic building blocks-beta-aminoketones-has been demonstrated.
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pubmed:language |
eng
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pubmed:journal |
|
|
pubmed:citationSubset |
IM
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pubmed:chemical |
|
|
pubmed:status |
MEDLINE
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|
pubmed:month |
Oct
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pubmed:issn |
1359-7345
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pubmed:author |
|
|
pubmed:issnType |
Print
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|
pubmed:day |
14
|
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pubmed:owner |
NLM
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|
pubmed:authorsComplete |
Y
|
|
pubmed:pagination |
4637-9
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pubmed:meshHeading |
|
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pubmed:year |
2008
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|
pubmed:articleTitle |
Highly enantioselective organocatalytic formation of a quaternary carbon center via chiral Brønsted acid catalyzed self-coupling of enamides.
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|
pubmed:affiliation |
Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Henkestrasse 42, 91054 Erlangen, Germany. tsogoeva@chemie.uni-erlangen.de
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|
pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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