Source:http://linkedlifedata.com/resource/pubmed/id/18768182
Switch to
Predicate | Object |
---|---|
rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1-2
|
pubmed:dateCreated |
2008-10-20
|
pubmed:abstractText |
Flavonol glycosides present in leaves of Maytenus ilicifolia, were examined after fractionation on silica-gel column. Flavonol mono-, di-, tri-, and tetraglycosides, containing kaempferol, quercetin or myricetin were identified by offline electrospray mass spectrometry. Increasing the cone energy induced to adducts variation, from H(+) to Na(+). Protonated ions were characteristically fragmented by sequentially removing the monosaccharide residues, whereas in the sodiated ions, the aglycone was firstly removed. Online high performance liquid chromatography-mass spectrometry, with simple gradients of water, acetonitrile and acetic acid indicated the presence of several isomers, which were further identified by gas chromatography-mass spectrometry as containing galactose or glucose.
|
pubmed:language |
eng
|
pubmed:journal | |
pubmed:citationSubset |
IM
|
pubmed:chemical | |
pubmed:status |
MEDLINE
|
pubmed:month |
Oct
|
pubmed:issn |
0021-9673
|
pubmed:author | |
pubmed:issnType |
Print
|
pubmed:day |
17
|
pubmed:volume |
1207
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
101-9
|
pubmed:dateRevised |
2009-1-15
|
pubmed:meshHeading |
pubmed-meshheading:18768182-Chromatography, High Pressure Liquid,
pubmed-meshheading:18768182-Flavonols,
pubmed-meshheading:18768182-Glycosides,
pubmed-meshheading:18768182-Isomerism,
pubmed-meshheading:18768182-Maytenus,
pubmed-meshheading:18768182-Plant Leaves,
pubmed-meshheading:18768182-Spectrometry, Mass, Electrospray Ionization
|
pubmed:year |
2008
|
pubmed:articleTitle |
Analysis of flavonol glycoside isomers from leaves of Maytenus ilicifolia by offline and online high performance liquid chromatography-electrospray mass spectrometry.
|
pubmed:affiliation |
Departamento de Bioquímica e Biologia Molecular, Universidade Federal do Paraná, CP 19046, CEP 81531-980, Curitiba-PR, Brazil.
|
pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
|