Source:http://linkedlifedata.com/resource/pubmed/id/18712907
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
37
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pubmed:dateCreated |
2008-9-15
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pubmed:abstractText |
We report on the triplet spectra and dynamics in two types of oligomeric films deposited by two different techniques: thermal evaporation and spin coating. The different molecular arrangement in both films is manifested in a red shift of the absorption, PL, and T1-Tn absorption spectra of the sublimated film relative to the spin-coated one. Triplet recombination dynamics studied with steady-state photoinduced absorption (PA) spectroscopy follow a dispersive bimolecular recombination model away from the trap filling regime. We obtained values for the triplet bimolecular recombination ratio (beta) of 3.4 x 10 (-14) and 1.1 x 10 (-15) cm3 s (-1) for evaporated and spin-coated film, respectively, the difference being attributed to diverse molecular arrangement in both films.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
1520-6106
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pubmed:author |
pubmed-author:Cabanillas-GonzalezJuanJ,
pubmed-author:CapelliRaffaellaR,
pubmed-author:GierschnerJohannesJ,
pubmed-author:HwuTsyr-YuanTY,
pubmed-author:LanzaniGuglielmoG,
pubmed-author:MucciniMicheleM,
pubmed-author:RamonMiguel CMC,
pubmed-author:SciasciaCalogeroC,
pubmed-author:ToffaninStefanoS,
pubmed-author:WongKen-TsungKT
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pubmed:issnType |
Print
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pubmed:day |
18
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pubmed:volume |
112
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
11605-9
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pubmed:year |
2008
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pubmed:articleTitle |
Molecular packing effects on the optical spectra and triplet dynamics in oligofluorene films.
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pubmed:affiliation |
IFN-CNR, Dipartimento di Fisica, ULTRAS-INFM, Politecnico di Milano, Milano 20133, Italy. juan.cabanillas@polimi.it
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pubmed:publicationType |
Journal Article
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