18688298

Source:http://linkedlifedata.com/resource/pubmed/id/18688298

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0001992, umls-concept:C0030011, umls-concept:C0233820, umls-concept:C0598002, umls-concept:C0681814, umls-concept:C1261322, umls-concept:C1510824, umls-concept:C1524062, umls-concept:C2603343
pubmed:issue	24
pubmed:dateCreated	2008-8-8
pubmed:abstractText	The gold-catalyzed aerobic oxidation of aldehydes proceeds through development of a partial negative charge and has a significant kinetic isotope effect (kH/kD = 2.8-2.9), which illustrates that activation of the C-H bond takes place in the rate-determining step.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/9610838
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jun
pubmed:issn	1359-7345
pubmed:author	pubmed-author:Bahn JohansenLouiseL, pubmed-author:FristrupPeterP, pubmed-author:Hviid ChristensenClausC
pubmed:issnType	Print
pubmed:day	28
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2750-2
pubmed:year	2008
pubmed:articleTitle	Mechanistic investigation of the gold-catalyzed aerobic oxidation of aldehydes: added insight from Hammett studies and isotopic labelling experiments.
pubmed:affiliation	Center for Sustainable and Green Chemistry, Technical University of Denmark, Kemitorvet, DK-2800 Lyngby, Denmark. pf@kemi.dtu.dk
pubmed:publicationType	Journal Article