Linked Life Data

18681413

Source:http://linkedlifedata.com/resource/pubmed/id/18681413

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
34
pubmed:dateCreated
2008-8-22
pubmed:abstractText
Ultrafast pump-probe spectroscopic studies have been performed on (C 5Me 5) 2U[- N=C(Ph)(CH 2Ph)] 2 and (C 5Me 5) 2Th[- N=C(Ph)(CH 2Ph)] 2 including, for the uranium complex, the first direct measurement of dynamics of electronic deactivation within a 5f-electron manifold. Evidence has been found for strong coupling between the electronic ground state and the f-electron manifold which dominates the dynamics of the excited states of the bis(ketimide) uranium complex. These also demonstrate strong singlet-f manifold coupling, which assists in the deactivation of the photoexcited state of the uranium complex, and provide information on intersystem crossing and internal conversion processes in both complexes.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
1520-5215
pubmed:author
pubmed:issnType
Electronic
pubmed:day
28
pubmed:volume
112
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7840-7
pubmed:year
2008
pubmed:articleTitle
Ultrafast spectroscopy of the uranium(IV) and thorium(IV) bis(ketimide) complexes (C5Me5)2An[-N=C(Ph)(CH2Ph)]2 (An = Th, U).
pubmed:affiliation
MPA-CINT, MS K771, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA. dhilton@uab.edu
pubmed:publicationType
Journal Article