Linked Life Data

18636725

Source:http://linkedlifedata.com/resource/pubmed/id/18636725

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
32
pubmed:dateCreated
2008-8-6
pubmed:abstractText
A study of the reaction of cis-[PdRf2(AsPh3)2] (Rf = 3,5-C6Cl2F3) with ISnBu3 (that is the reversal of the natural Stille reaction of [PdRfI(AsPh3)2] with RfSnBu3) allows for the observation of cis-[PdRf2(AsPh3)(ISnBu3)], the expected intermediate from a cyclic transmetalation in the direct Stille reaction, thus providing experimental support to the operation of cyclic transmetalation pathways.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Aug
pubmed:issn
1520-5126
pubmed:author
pubmed:issnType
Electronic
pubmed:day
13
pubmed:volume
130
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
10518-20
pubmed:dateRevised
2009-1-8
pubmed:year
2008
pubmed:articleTitle
Observation of a hidden intermediate in the Stille reaction. Study of the reversal of the transmetalation step.
pubmed:affiliation
IU CINQUIMA/Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, E-47071 Valladolid, Spain.
pubmed:publicationType
Journal Article