Source:http://linkedlifedata.com/resource/pubmed/id/18594951
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
1
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pubmed:dateCreated |
2009-2-5
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pubmed:abstractText |
GdAl3(BO3)4 polycrystals co-doped with Yb3+ and Eu3+ has been synthesised by combustion method with urea. Upon the excitation at 465 nm (Eu3+/7F6-->5D2 transition), emission bands centered at 590, 613, 697 and 702 nm in the wavelength region of 550-750 nm have clearly been observed, assigned to the electronic transitions of 5D0-->7FJ (J=1, 2, 4 and 5) of Eu3+ ions, respectively. Meanwhile, an intense emission centred at 980 nm along with a shoulder at 1,040 nm has also been observed by exploiting a cross-relaxation process between the transitions of Eu3+/5D0-->7F6 and Yb3+/2F7/2-->2F5/2. On the contrary, an intense red up-conversion emission centred at 613 nm originated from the 5D0-->7F2 transition of Eu3+ has been observed upon excitation with 980 nm laser diode. The quadratic dependence of the red up-conversion intensity on the pump-laser power reveals a cooperative energy transfer mechanism from a pair of Yb3+ ions to one Eu3+ ion.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Borates,
http://linkedlifedata.com/resource/pubmed/chemical/Erbium,
http://linkedlifedata.com/resource/pubmed/chemical/Gadolinium,
http://linkedlifedata.com/resource/pubmed/chemical/Polymers,
http://linkedlifedata.com/resource/pubmed/chemical/Ytterbium,
http://linkedlifedata.com/resource/pubmed/chemical/gadolinium trialuminum borate
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pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1053-0509
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
19
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
105-9
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pubmed:meshHeading |
pubmed-meshheading:18594951-Borates,
pubmed-meshheading:18594951-Crystallization,
pubmed-meshheading:18594951-Erbium,
pubmed-meshheading:18594951-Gadolinium,
pubmed-meshheading:18594951-Luminescent Measurements,
pubmed-meshheading:18594951-Polymers,
pubmed-meshheading:18594951-Powder Diffraction,
pubmed-meshheading:18594951-Sensitivity and Specificity,
pubmed-meshheading:18594951-Spectrometry, Fluorescence,
pubmed-meshheading:18594951-Spectrophotometry, Ultraviolet,
pubmed-meshheading:18594951-Spectroscopy, Near-Infrared,
pubmed-meshheading:18594951-Time Factors,
pubmed-meshheading:18594951-Ytterbium
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pubmed:year |
2009
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pubmed:articleTitle |
Synthesis and spectroscopic properties of GdAl3(BO3)4 poly-crystals codoped with Yb3+ and Eu3+.
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pubmed:affiliation |
MOE Key Lab of Specially Functional Materials, South China University of Technology, Guangzhou, 510640, People's Republic of China.
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pubmed:publicationType |
Journal Article
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