Source:http://linkedlifedata.com/resource/pubmed/id/18580978
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
26
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| pubmed:dateCreated |
2008-6-26
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| pubmed:abstractText |
Substitution of Cl(-) in the tricyclic triphosphorus cage Cl(P(1))-P3(CBu(t))2 by a range of both anionic and neutral nucleophiles has been investigated. With anionic nucleophiles, reaction with fluoride and hydride anion was shown to afford F(P(1))-P3(CBu(t)) and H(P(1))-P3(CBu(t))2 respectively. Subsequent deprotonation of the latter results in the formation of the aromatic anion [1,2,4-P3(CBu(t))2]-. With neutral nucleophiles, addition of either PMe3 or PEt3 to Cl(P(1))-P3(CBu(t))2 in the presence of TlOTf results in the formation of the phosphine-phosphenium complexes [(R3P(P(1))-P3(CBu(t))2][OTf] (R = Me or Et): the structure of the methyl-substituted compound was determined by a single crystal X-ray diffraction study. The phosphine ligand in these complexes is extremely labile and addition of I2 to [(Me3P(P(1))-P3(CBu(t))2]+ results in the formation of I(P(1))-P3(CBu(t))2.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jul
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| pubmed:issn |
1477-9226
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
14
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
3422-8
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| pubmed:year |
2008
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| pubmed:articleTitle |
Nucleophilic substitution reactions of the tricyclic triphosphorus cage P3(CBu(t))2: a novel route to polyphosphorus phosphenium complexes.
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| pubmed:affiliation |
Department of Chemistry, University of York, Heslington, York, UK.
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| pubmed:publicationType |
Journal Article
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