18563899

Source:http://linkedlifedata.com/resource/pubmed/id/18563899

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0020286, umls-concept:C0332514, umls-concept:C0914797, umls-concept:C1292724, umls-concept:C1504071
pubmed:issue	28
pubmed:dateCreated	2008-7-9
pubmed:abstractText	An iridium carbene oxazoline complex was used to catalyze hydrogenations of trisubstituted alkenes to give terminal and internal 1,3-hydroxymethyl chirons. The products are accessible in all possible stereoisomeric forms. These hydrogenations do not require strongly coordinating functionalities on the substrate, and in some key cases, catalyst- rather than substrate-controlled stereoselectivities are observed. It is hypothesized that these reactions would not be feasible using iridium or rhodium diphosphine complexes.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jul
pubmed:issn	1520-5126
pubmed:author	pubmed-author:BurgessKevinK, pubmed-author:ZhuYeY
pubmed:issnType	Electronic
pubmed:day	16
pubmed:volume	130
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	8894-5
pubmed:year	2008
pubmed:articleTitle	Asymmetric hydrogenation approaches to valuable, acyclic 1,3-hydroxymethyl chirons.
pubmed:affiliation	Department of Chemistry, Texas A & M University, Box 30012, College Station, Texas 77841, USA.
pubmed:publicationType	Journal Article