Source:http://linkedlifedata.com/resource/pubmed/id/18549211
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
27
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pubmed:dateCreated |
2008-7-3
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pubmed:abstractText |
The one-electron reduction of [Pd3(C7H7)2(CH3CN)3][BF4]2 in acetonitrile resulted in the formation of the dimer dication [Pd6(C7H7)4(CH3CN)4][BF4]2, whose structure containing a novel bitriangle hexapalladium skeleton was determined by X-ray crystallographic analysis. The dimer is stable in CD3CN at ambient temperature for several days but is highly air-sensitive. Similarly, the cycloheptatriene tripalladium complex [Pd3(C7H7R)2(CH3CN)3][BF4]2 (R = H, t-Bu) dimerized upon one-electron reduction. Both monomer and dimer of cycloheptatriene complexes were structurally determined by X-ray crystallographic analyses.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1520-5126
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
9
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pubmed:volume |
130
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
8586-7
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pubmed:dateRevised |
2008-12-22
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pubmed:year |
2008
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pubmed:articleTitle |
Reductive coupling of metal triangles in sandwich complexes.
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pubmed:affiliation |
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, and PRESTO, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871, Japan. tetsu@chem.eng.osaka-u.ac.jp
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pubmed:publicationType |
Journal Article
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