18543940

Source:http://linkedlifedata.com/resource/pubmed/id/18543940

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007886, umls-concept:C0038739, umls-concept:C0178499
pubmed:issue	14
pubmed:dateCreated	2008-7-10
pubmed:abstractText	Regio- and stereoselective hydroamidation of 1-alkynylphosphine sulfides proceeds in the presence of cesium carbonate to provide (E)-2-amino-1-thiophosphinyl-1-alkenes. Asymmetric hydrogenation of the adducts catalyzed by an iridium complex followed by desulfidation yields 2-amino-1-phosphinoalkanes, which offers a new approach to chiral N,P-ligands that will potentially serve as ligands in asymmetric reactions.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jul
pubmed:issn	1523-7060
pubmed:author	pubmed-author:KantehFF, pubmed-author:OshimaKoichiroK, pubmed-author:YorimitsuHidekiH
pubmed:issnType	Print
pubmed:day	17
pubmed:volume	10
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	3093-5
pubmed:year	2008
pubmed:articleTitle	Regio- and stereoselective hydroamidation of 1-alkynylphosphine sulfides catalyzed by cesium base.
pubmed:affiliation	Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto, Japan.
pubmed:publicationType	Journal Article