Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2008-6-12
pubmed:abstractText
Platinum (Pt) nanoparticles encapsulated in microporous carbon with a hollow structure (nPt@hC) were fabricated on the basis of a titanium(IV) oxide (TiO2) photocatalytic reaction. From the tomogram of a sample studied by using a transmission electron microscope (TEM), the Pt nanoparticles were found to be embedded in the carbon shell and were physically separated from each other by the carbon matrix. Owing to this unique structure, the Pt particles showed high resistance to sintering when subjected to thermal treatment at temperatures up to 800 degrees C. As a result, hydrogenation reactions using various heat-treated nPt@hCs as catalysts indicated that loss of catalytic activity was minimized. Thus, the present system will be a promising system for optimizing catalyst nanostructures utilized in processes requiring rigorous conditions.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
24
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6307-12
pubmed:year
2008
pubmed:articleTitle
High sintering resistance of platinum nanoparticles embedded in a microporous hollow carbon shell fabricated through a photocatalytic reaction.
pubmed:affiliation
Research Center for Solar Energy Chemistry, Osaka University, 1-3 Machikaneyama, Toyonaka 560-8531, Japan.
pubmed:publicationType
Journal Article