18452005

Source:http://linkedlifedata.com/resource/pubmed/id/18452005

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0016327, umls-concept:C0220781, umls-concept:C0259889, umls-concept:C1414863, umls-concept:C1883254
pubmed:issue	10
pubmed:dateCreated	2008-5-2
pubmed:abstractText	The electrophilic fluorodesilylation of enantioenriched allenylsilanes proceeds with efficient transfer of chirality. The silylation-fluorination of propargylic alcohols occurs with overall retention of stereochemistry, a result consistent with a stereospecific anti S(E)2' mechanism for the fluorination step.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101154995
pubmed:status	PubMed-not-MEDLINE
pubmed:month	May
pubmed:issn	1477-0520
pubmed:author	pubmed-author:CarrollLaurenceL, pubmed-author:ClaridgeTimothy D WTD, pubmed-author:GouverneurVéroniqueV, pubmed-author:McCulloughSamanthaS, pubmed-author:ReayW AWA
pubmed:issnType	Print
pubmed:day	21
pubmed:volume	6
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1731-3
pubmed:year	2008
pubmed:articleTitle	Stereospecific anti SE2' fluorination of allenylsilanes: synthesis of enantioenriched propargylic fluorides.
pubmed:affiliation	University of Oxford, Chemistry Research Laboratory, 12 Mansfield Road, Oxford, UK OX1 3TA.
pubmed:publicationType	Journal Article