Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
15
pubmed:dateCreated
2008-4-24
pubmed:abstractText
Core excitation triggers nuclear dynamics on the femtosecond time scale. A multiparametric electron/ion coincidence approach has been used to disentangle complex decay processes occurring at short (molecular) or long (atomic) time scales. Methyl chloride has been excited by scanning along the dissociative Cl2p-->sigma* resonance. The detailed chronology of the competing decay processes, leading to either the rearrangement product HCl(+), or an ultrafast dissociation leading to Cl(+), has been investigated. The observed Auger-Doppler shift has been analyzed for various orientations of the electron and fragment ion.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
0021-9606
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:volume
128
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
154314
pubmed:year
2008
pubmed:articleTitle
Multipathway dissociation dynamics of core-excited methyl chloride probed by high resolution electron spectroscopy and Auger-electron-ion coincidences.
pubmed:affiliation
Synchrotron SOLEIL, l'Orme des Merisiers, Saint-Aubin, Gif-sur-Yvette Cedex, France. catalin.miron@synchrotron-soleil.fr
pubmed:publicationType
Journal Article