Source:http://linkedlifedata.com/resource/pubmed/id/18410097
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
18
|
| pubmed:dateCreated |
2008-5-1
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| pubmed:abstractText |
This Communication reports simultaneous tracking of structural and kinetic information for the photoinduced elimination reaction of 1,2-diiodotetrafluoroethane in solution by transient X-ray diffraction. The transient structure of .CF2CF2I is determined to be a classical mixture whereas .CH2CH2I is bridged. Compared with the gas phase reaction, the secondary dissociation of .CF2CF2I into C2F4 and I is slowed down by a factor of 6 in solution. Transient X-ray diffraction offers a complementary method for capturing transient structures in solution which might be invisible or "optically silent" in time-resolved optical spectroscopy.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
May
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| pubmed:issn |
1520-5126
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| pubmed:author | |
| pubmed:issnType |
Electronic
|
| pubmed:day |
7
|
| pubmed:volume |
130
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
5834-5
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| pubmed:dateRevised |
2008-12-15
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| pubmed:year |
2008
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| pubmed:articleTitle |
Capturing transient structures in the elimination reaction of haloalkane in solution by transient X-ray diffraction.
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| pubmed:affiliation |
Center for Time-Resolved Diffraction, Department of Chemistry, KAIST, Daejeon 305-701, Korea.
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| pubmed:publicationType |
Journal Article
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