| pubmed-article:18389118 | pubmed:abstractText | Tris(2-pyridylthio)methane (tptmH) reacts with ZnCl(2) producing the Zn-C containing complex of [ZnCl(tptm)], whose cyclic voltammogram shows an irreversible oxidation peak at 0.2 V vs. E(0')(Fc(+/0)). DFT calculations suggested that 1e(-) oxidation should occur at the tptm ligand resulting in the cleavage of the Zn-C bond, leading to decomposition of the complex. | lld:pubmed |
