Source:http://linkedlifedata.com/resource/pubmed/id/18389118
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
11
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| pubmed:dateCreated |
2008-4-4
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| pubmed:abstractText |
Tris(2-pyridylthio)methane (tptmH) reacts with ZnCl(2) producing the Zn-C containing complex of [ZnCl(tptm)], whose cyclic voltammogram shows an irreversible oxidation peak at 0.2 V vs. E(0')(Fc(+/0)). DFT calculations suggested that 1e(-) oxidation should occur at the tptm ligand resulting in the cleavage of the Zn-C bond, leading to decomposition of the complex.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
|
| pubmed:issn |
1359-7345
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
21
|
| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
1314-6
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| pubmed:year |
2008
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| pubmed:articleTitle |
Synthesis and characterization of tris(2-pyridylthio)methanido Zn complex with a Zn-C bond and DFT calculation of its one-electron oxidized species.
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| pubmed:affiliation |
Department of Material Science and Chemistry, Osaka City University, Sumiyoshi-ku, Osaka, Japan.
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| pubmed:publicationType |
Journal Article
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