Source:http://linkedlifedata.com/resource/pubmed/id/18354777
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
13
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pubmed:dateCreated |
2008-3-20
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pubmed:abstractText |
The aerial oxidation of cobalt(II) salt, in a methanolic solution, containing a hydrazone ligand, (E)-N'-(4-oxo-4-phenylbutan-2-ylidene)benzohydrazide (condensation product of benzoyl acetone and benzhydrazide, LH2) leads to the coupling of two such ligand units through the formation of a rather long C-C bond [1.601(6) A] giving rise to a dinuclear Co (III) hydrazone complex, [Co2(L)2(L')(].0.25H2O (L' = C-C coupled hydrazone ligand). The structure of the complex has been determined by X-ray crystallography and IR, UV-Vis spectroscopy and elemental analysis have characterized the complex.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1477-9226
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
7
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1783-6
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pubmed:year |
2008
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pubmed:articleTitle |
Synthesis and structural characterization of a novel dinuclear complex compound formed by the aerial oxidation of cobalt(II) having an interligand C-C sigma-bond.
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pubmed:affiliation |
Department of Chemistry, Jadavpur University, Kolkata, 700 032, India.
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pubmed:publicationType |
Journal Article
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