Linked Life Data

18354761

Source:http://linkedlifedata.com/resource/pubmed/id/18354761

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2008-3-20
pubmed:abstractText
Poly-(n)-topic ligands with a linear arrangement of coordination pockets self-assemble, generally in high yield, to produce square [n x n] grid complexes. Oligomeric, non-grid intermediates, identified by structural studies, have shown alternative construction pathways, but have also indicated possible mechanistic routes to grid assembly. Various factors are considered critical to grid formation, including reaction pH, metal ion identity, CFSE, and metal ion redox behaviour. Ultimately the design of the ligand is pivotal to successful grid self-assembly, and the size of the [n x n] grid is largely limited only by the synthetic limitations of the ligands themselves.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
7
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1661-75
pubmed:year
2008
pubmed:articleTitle
Ligand directed self-assembly of polymetallic [n x n] grids: rational routes to large functional molecular subunits?
pubmed:affiliation
Department of Chemistry, Memorial University, St.John's, Newfoundland A1B 3X7, Canada.
pubmed:publicationType
Journal Article