Source:http://linkedlifedata.com/resource/pubmed/id/18345683
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
8
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pubmed:dateCreated |
2008-4-11
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pubmed:abstractText |
Irradiation of 2-(3-alkenyl)allenylphenyl azides in the presence of excess CuI furnished functionalized 2,3-cyclopentenylindoles in good yield with only trace amounts of competitive C-N-bonded regioisomeric products. These results represent a significant departure from the modest-to-nonexistent regioselectivity that attended thermal cyclization of these allenyl azide substrates.
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pubmed:grant | |
pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/18345683-15058962,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18345683-16805565,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18345683-17506552,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18345683-17530848
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
17
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pubmed:volume |
10
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1665-8
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pubmed:dateRevised |
2010-9-21
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pubmed:meshHeading | |
pubmed:year |
2008
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pubmed:articleTitle |
Allenyl azide cycloaddition chemistry. photochemical initiation and CuI mediation leads to improved regioselectivity.
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pubmed:affiliation |
Department of Chemistry, The Pennsylvania State University, University Park, PA 16802, USA. ksf@chem.psu.edu
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.,
Research Support, N.I.H., Extramural
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