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rdf:type |
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lifeskim:mentions |
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pubmed:issue |
7
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pubmed:dateCreated |
2008-3-27
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pubmed:abstractText |
A variety of chroman spiroketals are synthesized via inverse-demand [4 + 2] cycloaddition of enol ethers and ortho-quinone methides (o-QMs). Low temperature o-QM generation in situ allows for the kinetic, diastereoselective construction of these motifs, providing entry to a number of unusual chroman spiroketal natural products.
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pubmed:grant |
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pubmed:commentsCorrections |
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-11045449,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-12353982,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-15128229,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-15609955,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-16706527,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-16774271,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-16808526,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-17645344,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-18044909,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-5447178,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-5764292,
http://linkedlifedata.com/resource/pubmed/commentcorrection/18336038-5955233
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
1523-7060
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
3
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pubmed:volume |
10
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
1477-80
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pubmed:dateRevised |
2011-11-17
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pubmed:meshHeading |
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pubmed:year |
2008
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pubmed:articleTitle |
Diastereoselective syntheses of chroman spiroketals via [4 + 2] cycloaddition of enol ethers and o-quinone methides.
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pubmed:affiliation |
Department of Chemistry and Biochemistry, University of California at Santa Barbara Santa Barbara, California 93106-9510, USA.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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