Source:http://linkedlifedata.com/resource/pubmed/id/18321799
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
3
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pubmed:dateCreated |
2008-4-8
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pubmed:abstractText |
The aim of this study was to introduce Ag-Cu phase nanopowder as an additive to improve the corrosion behavior of dental amalgams. A novel Ag-Cu nanopowder was synthesized by the precipitation method. An amalgam alloy powder (World-Cap) was added and mixed with 5 wt.% and 10 wt.% of Ag-Cu nanopowders, respectively, to form experimental amalgam alloy powders. The original alloy powder was used as a control. Alloy powders were examined using X-ray diffraction, transmission electron microscopy (TEM), scanning electron microscopy and electron probe microanalysis. Amalgam disk specimens of metallurgically prepared were tested in 0.9% NaCl solution using electrochemical methods. The changes in the corrosion potential and anodic polarization characteristics were determined. Corrosion potential data were analyzed statistically (n=3, analysis of variance, Tukey's test, p<0.05). The diameters of lamellar structure Ag-Cu nanoparticles were measured to be approximately 30 nm. The composition of the Ag-Cu nanoparticles determined by TEM-energy-dispersive spectroscopy was 56.28 at.% Ag-43.72 at.% Cu. A light-shaded phase was found mixing with dark Cu-Sn reaction particles in the reaction zones of Ag-Cu nanoparticle-doped amalgams. The Ag-Cu nanoparticle-doped amalgams exhibited zero current potentials more positive than the control (p<0.05) and no current peak was observed at -325mV that related to Ag-Hg phase and Cu6Sn5 phase in anodic polarization curves. The results indicated that the corrosion resistance of high-copper single-composition amalgam could be improved by Ag-Cu nanoparticle-doping.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
May
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pubmed:issn |
1742-7061
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
4
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
717-24
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pubmed:meshHeading |
pubmed-meshheading:18321799-Copper,
pubmed-meshheading:18321799-Dental Amalgam,
pubmed-meshheading:18321799-Electrochemistry,
pubmed-meshheading:18321799-Nanoparticles,
pubmed-meshheading:18321799-Potentiometry,
pubmed-meshheading:18321799-Silver,
pubmed-meshheading:18321799-Solutions,
pubmed-meshheading:18321799-X-Ray Diffraction
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pubmed:year |
2008
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pubmed:articleTitle |
Morphology and electrochemical behavior of Ag-Cu nanoparticle-doped amalgams.
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pubmed:affiliation |
Division of Dental Materials Science, Department of Restorative Dentistry, University of Washington, Seattle, WA, USA.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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