Source:http://linkedlifedata.com/resource/pubmed/id/18275183
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| Predicate | Object |
|---|---|
| rdf:type | |
| pubmed:issue |
10
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| pubmed:dateCreated |
2008-3-6
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| pubmed:abstractText |
Ultrafast optical Kerr effect spectroscopy has been used to study the temperature-dependent orientational dynamics of 1,n-dicyano n-alkane liquids ranging from dicyanomethane to 1,8-dicyanooctane. The dependence of the reorientational times on temperature and viscosity is consistent with the molecules adopting a largely extended structure in the liquid state, with a preference for gauche conformations at the methylenes bonded to the cyanide groups. The data are also suggestive of temperature-dependent, collective structural rearrangements in these liquids.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Mar
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| pubmed:issn |
1520-6106
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
13
|
| pubmed:volume |
112
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
3115-20
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| pubmed:year |
2008
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| pubmed:articleTitle |
temperature-dependent orientational dynamics of 1,n-dicyano n-alkanes.
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| pubmed:affiliation |
Department of Chemistry and Biochemistry, Institute for Physical Science and Technology, Maryland NanoCenter, University of Maryland, College Park, MD 20742, USA.
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| pubmed:publicationType |
Journal Article
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