Source:http://linkedlifedata.com/resource/pubmed/id/18260664
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
9
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pubmed:dateCreated |
2008-2-28
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pubmed:abstractText |
We report dramatic improvements in the stability and crystallinity arising from partial fluorination of soluble anthradithiophene derivatives. These fluorinated materials still behave as p-type semiconductors but with dramatic increases in thermal and photostability compared to the non-fluorinated derivatives. The triethylsilyl-substituted material forms highly crystalline films even from spin-cast solutions, leading to devices with maximum hole mobility greater than 1.0 cm(2)/V s. In contrast, the triisopropylsilyl derivative forms large, high-quality crystals that could serve as the substrate for transistor fabrication. For this compound, mobility as high as 0.1 cm(2)/V s was measured on the free-standing crystal.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Mar
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pubmed:issn |
1520-5126
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pubmed:author | |
pubmed:issnType |
Electronic
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pubmed:day |
5
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pubmed:volume |
130
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2706-7
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pubmed:meshHeading |
pubmed-meshheading:18260664-Crystallization,
pubmed-meshheading:18260664-Heterocyclic Compounds with 4 or More Rings,
pubmed-meshheading:18260664-Hydrocarbons, Fluorinated,
pubmed-meshheading:18260664-Molecular Structure,
pubmed-meshheading:18260664-Semiconductors,
pubmed-meshheading:18260664-Solubility,
pubmed-meshheading:18260664-Stereoisomerism,
pubmed-meshheading:18260664-Thiophenes
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pubmed:year |
2008
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pubmed:articleTitle |
Chromophore fluorination enhances crystallization and stability of soluble anthradithiophene semiconductors.
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pubmed:affiliation |
Department of Chemistry, University of Kentucky, Lexington, Kentucky 40506, USA.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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