Linked Life Data

18247921

Source:http://linkedlifedata.com/resource/pubmed/id/18247921

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
2008-2-5
pubmed:abstractText
We report a pump-probe femtosecond transient absorption spectroscopic study on the electron transfer reaction of CCl(4) in liquid ethanol. By direct observations of the presolvated electron and of the reaction transition state CCl(4) (*-), this study provides direct evidence of the resonant dissociative electron transfer (RDET) of the presolvated electron to CCl(4). Moreover, the lifetime of CCl(4) (*-) in ethanol is directly obtained from the decay kinetics and its measured value is found to be nearly identical to its gas-phase value. Hence, these results also imply that RDET can be an efficient process in an aqueous environment.
pubmed:commentsCorrections
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
0021-9606
pubmed:author
pubmed:issnType
Print
pubmed:day
28
pubmed:volume
128
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
041102
pubmed:dateRevised
2008-10-24
pubmed:meshHeading
pubmed:year
2008
pubmed:articleTitle
Resonant dissociative electron transfer of the presolvated electron to CCl4 in liquid: Direct observation and lifetime of the CCl4*- transition state.
pubmed:affiliation
Department of Physics and Astronomy and Department of Chemistry, University of Waterloo, 200 University Ave. West, Waterloo, Ontario N2L 3G1, Canada.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't