Source:http://linkedlifedata.com/resource/pubmed/id/18232928
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
2
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pubmed:dateCreated |
2008-1-31
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pubmed:abstractText |
High-resolution x-ray absorption and emission spectra of liquid water exhibit a strong isotope effect. Further, the emission spectra show a splitting of the 1b1 emission line, a weak temperature effect, and a pronounced excitation-energy dependence. They can be described as a superposition of two independent contributions. By comparing with gas phase, ice, and NaOH/NaOD, we propose that the two components are governed by the initial state hydrogen bonding configuration and ultrafast dissociation on the time scale of the O 1s core hole decay.
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pubmed:commentsCorrections | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
0031-9007
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
18
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pubmed:volume |
100
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
027801
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pubmed:dateRevised |
2008-8-12
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pubmed:year |
2008
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pubmed:articleTitle |
Isotope and temperature effects in liquid water probed by x-ray absorption and resonant x-ray emission spectroscopy.
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pubmed:affiliation |
Universität Würzburg, Experimentelle Physik II, Am Hubland, 97074 Würzburg, Germany. oliver.fuchs@physik.uni-wuerzburg.de
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pubmed:publicationType |
Journal Article
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